"PVN: Player VS Non Player Character" is the thirteen and final episode of the Overlord Anime adaptation. It was first broadcasted on September 29, 2015.
- Ainz Ooal Gown defeats and kills Shalltear Bloodfallen.
- Ainz resurrects Shalltear Bloodfallen.
- Shalltear's Rebellion ends.
- The cardinals meeting in the Slane Theocracy.
- Nfirea Bareare and Lizzie Bareare moved to Carne Village.
- Sebas Tian and Solution Epsilon are now in the Royal Capital.
- Gazef Stronoff found Brain Unglaus on the alley in the Royal Capital.
- Momon and Nabe are promoted to adamantite ranked adventurer.
In Order of Appearance
- Shalltear Bloodfallen
- Ainz Ooal Gown
- Touch Me (Mentioned Only)
- Warrior Takemikazuchi (Mentioned Only)
- Peroroncino (Mentioned Only)
- Bukubukuchagama (Voice Only)
- Aura Bella Fiora
- Mare Bello Fiore
- Pandora's Actor
- Yuri Alpha
- CZ2128 Delta
- Entoma Vasilissa Zeta
- Ulbert Alain Odle (Silhouette)
- Tabula Smaragdina (Silhouette)
- Captain of the Black Scripture
- Kaire (Mentioned Only)
- Nigun Grid Luin (Mentioned Only)
- Nfirea Bareare
- Lizzie Bareare
- Narberal Gamma
- Goblin Troop
- Enri Emmot
- Nemu Emmot
- Lupusregina Beta
- Sebas Tian
- Solution Epsilon
- Gazef Stronoff
- Brain Unglaus
- Gargantua (Mentioned Only)
- Victim (Mentioned Only)
- Nishikienrai (Mentioned Only)
- Perfect Warrior
- Fallen Down
- Breath Composition
- The Six Cardinals having a meeting with the Captain of the Black Scripture.
- Narberal Gamma escorts Nfirea Bareare and Lizzie Bareare to Carne Village.
- Lupusregina Beta is given a mission to spy in Carne Village and protects three people.
- Bellote wasn't in the Adventurer's Guild when Momon and Nabe entered the Guild after their promotion to adamantite ranked adventurer.